Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Stress corrosion cracking of ductile niresist irons and. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70%. The relative resistance to chloride scc is dependant on the stainless steel family. Considerable data and a variety of procedures for dealing with matters related to the bwr pipe cracking problem have been developed. One of the most important forms of stress corrosion cracking can be stress corrosion cracking deriving from chloride, which it can be assumed as a type of intergranular corrosion meng, 2003. A constant load scc test was conducted on the candidate materials in air after deposition of simulated sea salt particles on the specimen gauge section. Typically, ubend samples are tested in this environment for periods up to 1008 hours, with interruptions to check for cracking. Initiation and propagation of stress corrosion cracking of. Astm g49 standard preparation and use of direct tension stress corrosion test specimens. If a susceptible material is placed in a corrosive environment under tension of. Astm g38 standard practice for making and using cring stress corrosion test specimens. Stress cracking of duplex stainless steel in refining materials. Experimental study on the stress corrosion cracking behavior of.
Intergranular stress corrosion cracking scc of pipelines has been known to cause. Selection of metallic materials for stress corrosion cracking resistance in sodium chloride environments 1. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The stress corrosion cracking scc behavior of aisi347 austenitic stainless steel. A sem bse image of a corrosion pit associated with stress corrosion cracking in a stainless steel drum. Behavior and susceptibility to stress corrosion cracking of a nickel. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Two cases of chloride stress corrosion cracking clscc of type 2205. Change the material to one that is more resistant to scc under the specific. Stress corrosion cracking scc near the fusion boundary of a 316ng stainless steel ss welded joint in hightemperature water was investigated with emphasis on the relation to the. Localized corrosion intergranular, pitting usually proceeds to scc. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. An accurate evaluation of stress corrosion cracking scc in. This document defines the design criteria that shall be used for the selection of metallic materials in order to prevent failure due to stress corrosion cracking.
In late 2003, it became nace mr0175 iso 15156, petroleum and natural gas industries materials for use in h 2. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of. Data for several nickel alloys and stainless steels are presented in table 3. Using resistant materials, properly applied coatings under insulation, low chloride water during hydrotesting, clean dry as quickly as. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620oc to 705oc, depending upon prior solution treating temperature. Stress corrosion cracking an overview sciencedirect topics. A sandvik grade with very good resistance to this form of stress corrosion cracking is sanicro 28. Sulfide stress cracking ssc testing southwest research. They should be considered for use only in cases where a suitable alloy cannot be found in table i. Intergranular stress corrosion cracking an overview. Sulfide stress cracking nace mr01752002, mr0175iso. Determination of stress corrosion cracking resistance of. Stress corrosion cracking behavior of nickel base alloys. Stress corrosion cracking and component failure indian academy.
For good resistance to h 2 sinduced stress corrosion cracking scc an alloy with high nickel content is recommended, and for most sour environments this type of alloy is now used. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. The advantageous effect of nickel on limiting the stress corrosion cracking in boiling 42% mgcl2 is observed. Xrd, sem, eds and ebsd analyses have been carried out to characterize the microstructure of the tested specimens. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Corrosion investigation metallurgical technologies, inc. This effect is significantly less common in ceramics which are typically more resilient to chemical attack. Stresscorrosion cracking failure analysis and prevention. Hampton, smirt post conference, lausanne, switzerland, august, 1987. The back scatter electron bse imaging mode of the scanning electron microscope is sensitive to. Its high molybdenum content makes it exceptionally resistant to pitting and crevice corrosion, and it is one of only a few materials that can withstand the corrosive effects of wet chlorine. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Sem fractograph of intergranular scc of type 316 stainless steel in. Magnified sem images of ig cracks in the edge region of the fracture surfaces.
N02200 and alloy 201 n02201 are the best materials for resisting corrosion and stress corrosion cracking in caustic environments. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Not only can duplex stainless steel hold up reliably through trauma impact, but through corrosion as well. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Scanning electron microscopy sem analysis of a cross section of the. A common solution for assessing the resistance of materials to this extremely destructive form of attack is boiling 45% magnesium chloride astm standard g 36. Resistance to stress corrosion cracking haynes international. This mode of attack is termed stress corrosion cracking scc. Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and. Intergranular cracking occurs when grainboundary regions are anodic to the main body of the metal and therefore less resistant to corrosion. The alloys comprising of 42 45% nickel will not be attacked in this.
Materials that testing and experience have shown to possess high resistance to stress corrosion cracking their use is given reference. Stress corrosion cracking scc is a common issue with many specialty alloys. Because of this, one must use caution when specifying materials for applications that involve. We have developed corrosion resistant alloys for uses such as paper mill rolls and conductor rolls. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. The impact of scc on a material usually falls between dry cracking and the fatigue. Sulfide stress cracking nace mr01752002, mr0175iso 15156 650 te c h n i c a l the details nace mr0175, sulfide stress corrosion cracking resistant metallic materials for oil field equipment is widely used throughout the world. Plastic failure through environmental stress cracking. Understanding of the failure mechanism of stress corrosion. Due to its good mechanical properties and reasonable corrosion resistance, cr martensitic stainless steel mss has been widely used as a structural material in.
Model test blocks of the exchangers were constructed with tubes expanded by. Stress corrosion cracking sandvik materials technology. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. The crack propagation is a result of the combined and synergistic interaction of mechanical tensile stresses and corrosion reactions. As the cracking penetrates farther into the material, it eventually reduces the effective supporting cross section to the point where the structure fails by overload or, in the case of vessels and piping, escape seepage of the contained. Depending on the process conditions, corrosion by co2 and h2s, chlorideinduced localised pitting or crevice corrosion, stress corrosion cracking andor h2sinduced sulphide stress cracking may be. Mechanical methods of improving resistance to stress corrosion cracking in bwr piping systems j. Astm g64 classification of resistance to stress corrosion cracking of heattreatable aluminum alloys. Sulfide stress cracking ssc testing hydrogen sulfide h 2 s is a naturally occurring gas that can be deadly to humans and corrosive to oil and gas equipment, especially in the presence of water. Corrosion behavior of inconel 625 heanjia super metals. Nickel and nickel base alloys are normally resistant to chloride stress corrosion cracking as compared to stainless steels. Stress corrosion cracking scc sandvik materials technology.
Analysis of fracture surfaces using scanning electron microscopy sem. Other problems that have been observed with inconel include wastage, tube denting, pitting, and intergranular attack. Under many circumstances, environmental stress cracking can occur simply under the moldedin residual stress associated with injection molding and other forming processes. A comparative study of localized corrosion and stress. The equivalent mechanism for crack growth under cyclic stresses is called corrosion fatigue cf, and crack growth here depends upon the stress ratio.
Failure analysis of corrosion on stainless steel fasteners. Stress corrosion cracking international institute of. The use of 316l would be more resistant to crevice corrosion attack. Resistance to atmospheric stress corrosion cracking scc and crevice corrosion was examined for various candidate canister materials in the spent fuel dry storage condition using concrete casks. Stress corrosion cracking scc behavior of alloy 617 was studied to.
The national association of corrosion engineers nace test method tm0177 is widely used to qualify metals for resistance to sulfide stress cracking. Stress corrosion cracking implies cracking due to combined effect of corrosion with stress. The resistance to scc of the material reflected by the behaviors of sem. Improved resistance to caustic stress corrosion cracking can be given to. This study investigated the corrosion and stress corrosion cracking susceptibility of 316l stainless steel exposed to 550 c and 600 c supercritical water. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The resistance of metals to stress corrosion cracking is always less when. To understand the corrosion resistance properties of duplex stainless steel, you must also understand the concept of stress corrosion cracking. Optical or scanning electron microscopy sem of failed sections may be required to fully identify them.
Stress corrosion cracking starts from corrosion sites at the material. Each alloy has specific corrosion resistance, high corrosion fatigue strength, andor high resistance to stress corrosion cracking, and it is used in special applications where standard corrosion resistant alloys are. Comparative stress corrosion cracking and general corrosion resistance of annealed and hardened 440c stainless steelnew techniques in stress corrosion testing m. A research on the corrosion and stress corrosion cracking. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Stress corrosion cracking scc is a timedependent process that occurs under the influence of residual or imposed tensile stress and specific corrosive environment. Super duplex materials, such as our zeron 100, and super austenitic alloys. Danford marshall space flight center, marshall space flight center, alabama april 1998. Stress corrosion cracking in duplex stainless steel.
Identifying incompatibility between a plastic resin and a chemical agent at the design and material selection stage can be the difference in avoiding failure. Chloride stress corrosion cracks were also found at the corrosion sites. Duplex is more resistant and nickel base alloys are highly resistant but not immune. This form of corrosion is particularly dangerous because it may not occur under a particular set of conditions until. Corrosion resistant metals materials selection guide. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Corrosion investigation engineering and metal corrosion testing services example 3. Scc table ii alloys and tempers listed in table ii are moderately resistant to stress corrosion cracking. Stress corrosion is another form of corrosion that is important to many fields including civil structures. This is a phenomenon where corrosionresistant materials such as stainless steel are cracked. The back scatter electron bse imaging mode of the scanning electron microscope is sensitive to compositional variations. The stress corrosion cracking scc of different aging states for 7050 aluminum alloy in 3.
Stresscorrosion occurs when a material exists in a relatively inert environment but corrodes due to an applied stress. Methods of improving resistance to stress corrosion cracking. The stress corrosion cracking in expanded parts of stainless steel heat exchangers and its prevention were studied. Stress corrosion cracking scc is defined as the growth of cracks due to the. This standard presents metallic material requirements to provide resistance to sulfide stress cracking ssc andor stress corrosion cracking scc for petroleum production, drilling, gathering and flow line equipment, and field processing facilities to be used in hydrogen. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. Duplex stainless steel has become more and more popular for its combination of strength and affordability. Stress corrosion cracking of ductile niresist irons and stainless steels. Stress corrosion cracking scc is interpreted to take place due to specific combinations of susceptible materials in suitable corrosion environments under adequate stress, specifically under constant stress, figure 1.